张海磊
张海磊，理学博士，教授，博士生导师，材料化学系教师党支部书记；比利时根特大学博士后/访问学者，合作导师为欧洲科学院院士Richard Hoogenboom教授。近年来，主持国家自然科学基金（面上和青年）、国家留学基金公派访问学者项目、中央引导地方科技发展资金项目、河北省自然科学基金等多项课题，以通讯/第一作者在Nat. Commun., J. Am. Chem. Soc., Angew. Chem. Int. Ed.等期刊发表SCI检索论文40余篇，主编出版教材《高分子专业英语》（化学工业出版社），省级示范课程项目负责人；入选河北省新时代冀青之星、河北省科技特派员、燕赵英才A，保定市青年智库专家，河北大学坤舆青年学者，河北大学青年拔尖人才；担任Smart Mol., Eng. Sci., Poly. Sci. Tech., ChemPhysMater等期刊青年编委，Chem. Soc. Rev., Angew. Chem. Int. Ed., Adv. Mater. Adv. Funct. Mater.等50余个同行评议期刊审稿人。2026年获河北省教学成果奖一等奖。中共河北大学第八届党代会代表。
一、联系方式
邮箱：zhanghailei@hbu.edu.cn
二、主讲课程
《高分子物理》《高分子材料专业英语》《材料与人类文明》
三、研究兴趣
1、刺激响应高分子基复合材料
2、生物医用高分子材料
3、生物与医药
四、荣誉及奖项
1、河北大学青年教师课堂教学比赛一等奖
2、保定市科技进步奖一等奖（第一完成人）
3、首届河北省“冀青之星”
4、首届河北大学青年五四奖章
5、河北大学优秀共产党员
6、“学习强国”优秀学习积极分子
7、河北大学暑期社会实践优秀指导教师
8、首届河北省大学生化学实验创新设计竞赛优秀指导教师奖
9、河北大学研究生教学成果奖特等奖（第三完成人）
五、基金项目
1. 国家自然科学基金面上项目，No. 22572042，激基缔合与大环限域协同构建水凝胶基柔性X射线荧光成像体系，2026.01-2029.12，50万，主持。
2. 国家自然科学基金青年基金，No. 22102045，基于X射线激发长余辉发光材料构建余辉光诱导水凝胶制备体系，2022.01-2024.12，30万，主持，已结题。
3. 国家留学基金委，No. 202108130104，超分子双网络水凝胶的构建，2023.02-2024.02，主持，已结题。
4. 中央引导地方科技发展资金项目，No. 226Z1301G，基于X射线长余辉发光材料构建体内原位3D打印系统，2022.07~2025.06，15万，已结题。
5. 河北省高等学校科学研究专项任务项目(基础研究重点培育)，No. JCZX2025011，基于镧系离子交联水凝胶构建X射线成像体系，2025.01~2027.12，20万，主持。
6. [教学项目]河北省研究生课程思政示范课程项目，YKCSZ2022007，2023.01~2023.12，主持，2万，已结题。
7. 河北省自然科学基金，B2019201138，基于埃洛石制备过氧化氢刺激响应型纳米胶囊， 2019.01~2021.12，主持，6万，已结题。
8 . [教学项目]河北省研究生示范课程立项建设项目，KCJSX2019009，聚合物制备中的综合设计，2020.01~2021.12，主持，2万，已结题。
9. 河北省高等学校科学技术研究项目，QN2018052，过氧化氢响应型埃洛石纳米管基载药荧光水凝胶的制备，2018.01~2020.12，主持，3万，已结题。
六、代表性论文
[1] Shanshan Li, Hailei Zhang*, Jiaying Zhong, Bo Zhang, Kaiming Zhang, Yuangong Zhang, Leipeng Li, Yanmin Yang, Yonggang Wu, and Richard Hoogenboom*. X-ray Induced Photodegradation of Hydrogels by the Incorporation of X-ray-activated Long Persistent Luminescent Nanoparticles. J. Am. Chem. Soc. 2025, 147, 20273-20283 (Cover art, 双一区TOP).
[2] Hailei Zhang,* Jiaying Zhong, Zetong Zhang, Kaiming Zhang, Yanmin Yang,* Leipeng Li, Yonggang Wu, and Richard Hoogenboom*. Photoresponsive Hexaarylbiimidazole-Crosslinked Hydrogels: From Synthesis to Diverse Applications. Angew. Chem. Int. Ed. 2025, 64, e20013 (双一区TOP).
[3] Chongyang Cai, Leipeng Li*, Xiaohuan Lv, Huimin Li, Tao Li, Pei Li, Wenting Zhao, Lingzhu Zi, Shiji Feng, Xuan Fan, Hailei Zhang, Dengfeng Peng*, Feng Wang*, Jianrong Qiu, and Yanmin Yang*. Nat. Commun., 2025, 16:6224 (双一区TOP).
[4] Hailei Zhang*, Bo Zhang, Chongyang Cai, Kaiming Zhang, Yu Wang, Yuan Wang, Yanmin Yang*, Yonggang Wu, Xinwu Ba, and Richard Hoogenboom*. Water-dispersible X-ray scintillators enabling coating and blending with polymer materials for multiple applications. Nat. Commun., 2024, 15: 2055 (highlighted by editorial board, 双一区TOP).
[5] Hailei Zhang*, Boyan Tang, Bo Zhang, Kai Huang, Shanshan Li, Yuangong Zhang, Haisong Zhang, Libin Bai, Yonggang Wu, Yongqiang Cheng, Yanmin Yang*, and Gang Han.* X-ray-activated polymerization expanding the frontiers of deep-tissue hydrogel formation. Nat. Commun., 2024, 15: 3247 (双一区TOP).
[6] Zetong Zhanga, Yujie Chena, Yuanyao Chen, Leipeng Li, Yonggang Wu, Yanmin Yang*, and Hailei Zhang*. Synthesis of Samarium-Incorporated X‑Ray-Sensitive Nanoparticles and Hydrogels: Diverse Applications in Radiation Monitoring and Dynamic Information Display. Smart Mol. 2026, DOI: 10.1002/smo2.70048 (双一区TOP).
[7] Yuan Wang, Zetong Zhang, Shichun Chen, Shaokai Zhang, Li Jia, Pan Li, Bo Zhang, Fang Gu* and Hailei Zhang*. Synthesis of Diaminopyridine-Incorpated Hydrogel Enables Colorimetric Sensoring, Responsive Swelling and Highly Adsorption Capacity of Copper(II). Eng. Sci., 2026, 40, 2103 (双一区TOP).
[8] Liuyang Wang, Xinyu Lu, Huijun Zhang, Bo Zhao, Hongchi Zhao, Yonggang Wu, Hailei Zhang*, Libin Bai*, Xinwu Ba. Aminated Halloysite-Based Cu/Poly(dimethylsiloxane) Nanofillers Enable Multifunctional Ethylene-Vinyl Acetate Random Copolymer Encapsulation Nanocomposites. Polymer, 2026, 363, 130544.
[9] Kaiming Zhang, Feng Liu, Tomáš Sedlačík, Zhe Wang, Lixin Sun, Hailei Zhang, Richard Hoogenboom. Ultra-stiff and tough dual-dynamic covalently crosslinked poly(2-isopropenyl-2-oxazoline) hydrogels. Eur. Poly. J. 2026, 257, 115061.
[10] Shichun Chen, Yongkang Han, Sihan Kou, Libin Bai, Yonggang Wu, Hailei Zhang*. Facile synthesis of halloysite nanotubes-based nanocomposite with room-temperature phosphorescence properties. ChemPhysMater, 2026, DOI: 10.1016/j.chphma.2026.06.
[11] Huabiao Chen, Weihua Song, Bo Zhang, Zetong Zhang, Yanmin Yang, Libin Bai, Yonggang Wu, and Hailei Zhang*. Halloysite-based X-ray-activated persistent luminescent hydrogels enable multiple-level encryption and dual-locked camouflage. Energy Environ. Mater., 2025, 8: e7034 (双一区TOP，IF = 14.1, 中国最具国际影响力学术期刊).
[12] Jiaying Zhong, Weihua Song*, Yu Wang, Jing Zhang, Yan Gao, Yanmin Yang, Hailei Zhang*. Developing halloysite-based X-ray scintillating nanocomposite enables red to green tunable emission behavior in epoxy resin. Applied Clay Science, 2025, 267: 107726.
[13] Yanfang Ma, Pengying Jia, Yelong Lu, Bo Zhang, Yonggang Wu, Hailei Zhang*. Tetraphenylethylene-modified Halloysite Nanotubes Enabling Cu(II)-sensitive Nanocomposite. J. Chin. Ceram. Soc., 2025, 53(12): 3545–3552.
[14] Yuan Wang, Xinwu Ba*, Bo Zhang, Yu Wang, Yonggang Wu, Hailei Zhang*. Halloysite nanotubes as nano-support matrix for programming the photo/H2O dual triggered reversible gel actuator. J. Colloid Interface Sci., 2024, 657: 344-351 (一区TOP).
[15] Pengying Jia, Yelong Lu,* Yuqing Yang, Xiaoyan Zhu, Hailei Zhang*, and Yonggang Wu*. A thermosensitive luminescence halloysite-based nanocomposite enabling encryptable thermal printing. Chem. Commun., 2024, 60: 6659-6662.
[16] Yu Wang, Jiaying Zhong, Huabiao Chen, Weihua Song, Hailei Zhang*, Yonggang Wu, and Xinwu Ba*. Exploration of halloysite-based nest-like microspheres as a multifunctional reinforcement of epoxy resin. Eur. Poly. J., 2024, 217: 113329.
[17] Xumin Ren, Hailei Zhang*, Bo Zhang, Hongchi Zhao, Yonggang Wu, Xinwu Ba*. Halloysite/phenol-formaldehyde nanocomposites with enhanced mechanical properties and lowered fire hazard. Appl. Clay Sci., 2023, 231: 106743.
[18] Jianjun Shi, Hailei Zhang*, Yu Wang, Xumin Ren, Xinwu Ba, Wei Wang*. Aminated Halloysite/Jute/Phenol-Formaldehyde Composites with Enhanced Mechanical Properties, Improved Lightweight Character, and Lowered Fire Hazard. ACS Appl. Eng. Mater., 2023, 1: 1575-1582.
[19] Bo Zhang, Shanshan Li, Yuan Wang, Yonggang Wu, Hailei Zhang*. Halloysite nanotube-based self-healing fluorescence hydrogels in fabricating 3D cube containing UV-sensitive QR code information. J. Colloid Interface Sci., 2022, 617, 353-362 (一区TOP).
[20] Jianceng Shi, Hailei Zhang*, Bo Zhang, Yu Wang, Libin Bai, Yonggang Wu, Xinwu Ba*. Halloysite nanotube-based nest-like composite microspheres with enhanced microwave absorption ability. Compo. Sci. Tech., 2022, 230: 109760 (一区TOP).
[21] Yelong Lu, Hongchi Zhao*, Xinrong Huang, Di Hu, Yonggang Wu, Xinwu Ba, Hailei Zhang*. Exploring maleimide-anchored halloysites as nanophotoinitiators for surface-initiated photografting strategies. Chem. Commun., 2022, 58: 13636–13639.
[22] Haiyun Fan, Pengying Jia, Hailei Zhang*, Zhiyi Su, Xinwu Ba, Yonggang Wu*. Pyrene-functionalized halloysite nanotubes for simultaneously detecting and separating Hg(ii) in aqueous media: A comprehensive comparison on interparticle and intraparticle excimers. Nanotech. Rev., 2022, 11(1): 2038-2049.
[23] Weihua Song, Jipeng You, Yuangong Zhang, Qi Yang, Jin Jiao, Hailei Zhang*. Recent Studies on Hydrogels Based on H2O2-Responsive Moieties: Mechanism, Preparation and Application. Gels, 2022, 8(6): 361.
[24] Qiang Zhao, Hanxi Jiang, Boyan Tang, Yonggang Wu, Xinwu Ba, Hailei Zhang*. Chemosensor-Anchored Halloysite Nanotubes for Detection and Removal of Hypochlorite in Water. ACS Appl. Nano Mater. 2021, 4, 7, 7435–7442.
[25] Boyan Tang, Hailei Zhang*, Cong Cheng, Hanxi Jiang, Libin Bai, Xinwu Ba, Yonggang Wu*. Development of halloysite nanotube-based hydrogel with colorimetric H2O2-responsive character. Appl. Clay Sci. 2021, 212: 106230.
[26] Yan Gao, Haisong Zhang*, Yanbo Zuo, Weihua Song, Libin Bai, Hailei Zhang*, Hongjie Wang, Yonggang Wu, Xinwu Ba*. Preparation of allylamine-grafted cellulose by Ce(IV): a desirable candidate of oral phosphate binders. Polym. Bull., 2021, 78: 2537-2552.
[27] Zhiyi Su, Hailei Zhang*, Yan Gao, Li Huo, Yonggang Wu, Xinwu Ba*. Coumarin-anchored halloysite nanotubes for highly selective detection and removal of Zn(II). Chem. Eng. J., 2020, 393: 124695 (双一区TOP).
[28] Cong Cheng, Yan Gao*, Weihua Song, Qiang Zhao, Haisong Zhang, Hailei Zhang*. Halloysite Nanotube-Based H2O2-Responsive Drug Delivery System with a Turn on Effect on Fluorescence for Real-Time Monitoring. Chem. Eng. J., 2020, 380: 122474 (双一区TOP，ESI高被引).
[29] Cong Cheng, Weihua Song*, Qiang Zhao, Hailei Zhang*. Halloysite Nanotubes in Polymer Science: Purification, Characterization, Modification and Applications. Nanotech. Rev., 2020, 9: 323–344.
[30] Yanfang Ma, Zhihang Zhao, Boyan Tang, Yonggang Wu, Hailei Zhang*. Facile preparation of polymer-grafted halloysite nanotubes via a redox system: a novel approach to construct antibacterial hydrogel. Macromol. Res., 2020, 28(10): 948-952.
[31] Yuangong Zhang; Libin Bai*, Cong Cheng; Qian Zhou; Zhou Zhang; Yonggang Wu, Hailei Zhang*. A Novel Surface Modification Method upon Halloysite Nanotubes: A Desirable Cross-Linking Agent to Construct Hydrogels. Appl. Clay Sci., 2019, 182(1): 105259.
[32] Hailei Zhang, Cong Cheng, Hongzan Song, Libin Bai, Yongqiang Cheng*, Xinwu Ba*, Yonggang Wu*. A Facile One-Step Grafting of Polyphosphonium onto Halloysite Nanotubes Initiated by Ce(IV). Chem. Commun., 2019, 55: 1040-1043.
[33] Xiaojie Ren, Hailei Zhang*, Meining Song, Cong Cheng, Hongchi Zhao*, Yonggang Wu*. One-Step Route to Ladder-Type C-N Linked Conjugated Polymers. Macromol. Chem. Phys., 2019, 9: 1900044.
[34] Feng Liu, Yonggang Wu,* Libin Bai, Xixi Peng, Hailei Zhang,* Yuangong Zhang, Puying An, Sujuan Wang, Gang Ma, Xinwu Ba*. Facile Preparation of Hyperbranched Glycopolymer via AB3* Inimer Promoted by a Hydroxy/Cerium (IV) Redox Process. Polym. Chem., 2018, 9: 5024-5031.
[35] Chaoying Hu, Weiping Chen, Haicui Yao, Xiaojie Ren, Hailei Zhang*, Hongchi Zhao*, Yonggang Wu*, Xinwu Ba. Facile Synthesis of Ladder-Type Polyacenes with Perylene-Fused-Pyrene Structures. Macromol. Chem. Phys., 2018, 219: 1800201.
[36] Xuejing Liu, Yuangong Zhang, Haijing Hao, Wanju Zhang, Libin Bai,* Yonggang Wu, Hongchi Zhao, Hailei Zhang,* Xinwu Ba. Facile Construction of a Hyperbranched Poly(acrylamide) Bearing Tetraphenylethene Units: A Novel Fluorescence Probe with a Highly Selective and Sensitive Response to Zn2+, RSC Adv., 2018, 8: 5776-5783.
[37] Feng Liu, Hailei Zhang,* Jingwei Dong, Yonggang Wu,* Weiwei Li.* Highly Efficient Synthesis of Ladder-Type Small Molecular and Polymer based on BN-Heteroacene. Asian J. Org. Chem., 2018, 7: 465-470.
[38] Xinying Qin, Chao Wang, Meining Song, Hailei Zhang*, Yonggang Wu*. Facile Grafting of Ionic Liquids onto Halloysite Nanotubes via An Atom Transfer Radical Polymerization Method. J. Polym. Mater., 2018, 35: 159-169.
[39] Feng Liu, Libin Bai, Hailei Zhang,* Hongzan Song, Liandong Hu, Yonggang Wu,* Xinwu Ba. Smart H2O2‑Responsive Drug Delivery System Made by Halloysite Nanotubes and Carbohydrate Polymers. ACS Appl. Mater. Interfaces, 2017, 9: 31626-31633 (一区TOP).
[40] Jingwei Dong, Zhihang Zhao, Rui Liu, Hailei Zhang,* Yonggang Wu, Xinwu Ba*. Investigation of a Halloysite-Based Fluorescence Probe with a Highly Selective and Sensitive “Turn-On” Response upon Hydrogen Peroxide. RSC Adv., 2017, 7: 55034-55043.
[41] Hailei Zhang*. Selective Modification of Inner Surface of Halloysite Nanotubes: A Review. Nanotech. Rev., 2017, 6: 573-581.
[42] Hailei Zhang, Tianfei Ren, Yunjing Ji, Lingui Han, Yonggang Wu*, Hongzan Song*, Libin Bai, Xinwu Ba. Selective Modification of Halloysite Nanotubes with 1-Pyrenylboronic Acid: A Novel Fluorescence Probe with Highly Selective and Sensitive Response to Hyperoxide. ACS Appl. Mater. Interfaces, 2015, 7: 23805–23811.
[43] Hailei Zhang, Xiaoyan Zhu, Yonggang Wu*, Hongzan Song*, Xinwu Ba. High-efficiency grafting of halloysite nanotubes by using p-conjugated polyfluorenes via ‘‘click’’ chemistry. J. Mater. Sci., 2015, 50:4387–4395.
[44] Hailei Zhang, Xiaozhong Hong, Xinwu Ba*, Bei Yu, Xin Wen, Sujuan Wang, Xuefei Wang, Lei Liu, Jinchong Xiao*. Synthesis, Physical Properties, and Photocurrent Behavior of Strongly Emissive Boron-Chelate Heterochrysene Derivatives, Asian J. Org. Chem., 2014, 3: 1121–1216.
七、参加学术会议
1. Hailei Zhang*, Yonggang Wu, Xinwu Ba. Surface chemical modification of halloysite nanotubes. ACS Spring 2021 Meeting, Invited report.
2. 张海磊*，武永刚，巴信武. 埃洛石纳米管基高分子复合材料在生物领域的应用. 2019年生物医用高分子材料学术大会暨海峡两岸学术会交流会, 口头报告.
3. Hailei Zhang*, Yonggang Wu, Xinwu Ba. Facile construction of polymer-grafted holloysite nanotubes by using a redox initiating system. ISNSC-11 & WFIM-3, Oral presentation.
4. Hailei Zhang*, Hongzan Song. Facile grafting of ionic liquids onto halloysite nanotubes via an atom transfer radical polymerization method. 255th National Meeting and Exposition of the American-Chemical-Society, Oral presentation.
5. 张海磊*，田月兰，张元功. 过氧化性响应型埃洛石纳米管基荧光探针及释药体系的研究, 中国化学会第31届学术年会, 优秀墙报奖.
6. 张海磊*. 具有X射线闪烁发光性能的高分子复合材料的研究, 2024年第五届全国功能高分子研讨会，邀请报告.
7. 张海磊*. 基于埃洛石纳米管表面改性构建X射线辐射发光材料及应用探究. 2024中国材料大会, 邀请报告.
8. 张海磊*. 高性能低成本柔性闪烁体材料的研发，2024白石山生命科学大会，邀请报告.
9. 张海磊*. 具有辐射发光性能的高分子复合材料的研究, 2024年高分子材料科学与工程研讨会, 口头报告.
10. Hailei Zhang*. Water dispersible X-ray scintillators enable diverse applications in polymer science. 2024 Sino-Belgian Symposium on Functional Polymer Materials, Invited report.
11. 张海磊*. X射线诱导级联反应体系的构建及其在聚合物材料领域的应用探究，2025全国辐射化学与空间辐射效应高端研讨会，口头报告.
12. 张海磊*. 非侵入式诱导高分子原位聚合体系的研究及其在生物医学领域的潜在应用，2025年第六届全国功能高分子研讨会，邀请报告.
13. Hailei Zhang*. X-ray-photoinitiation cascade reaction expanding the frontiers of deep-tissue hydrogel formation, The 4th International Symposium for Advanced Gel Materials & Soft Matters (2025), Poster.
14. 张海磊*. X射线刺激响应型水凝胶体系的研究及在生物医学领域的潜在应用. 2025中国材料大会，口头报告.
15. Hailei Zhang*. Development of X-ray scintillating polymer composites enables diverse applications in biomedical field, The 8th International Conference on Enginnered Science (2025), Invited report.
16. 张海磊*. X射线-光化学级联反应体系的构建. 第十七届全国发光学会议（2025），邀请报告.
17. Hailei Zhang. X-ray Induced Photodegradation of Hydrogels by Incorporation of X-ray-activated Long Persistent Luminescent Nanoparticles. The 9th International Symposium on Polymer Chemistry (PC2025), Oral report.
18. 张海磊*. X射线-光化学级联反应体系的构建及其在生物医学领域的潜在应用. 2025全国高分子学术论文报告会，口头报告.
19. 张海磊*. 基于X射线长余辉发光材料的智能响应体系. 2026 国际能源与智能材料科技创新大会，邀请报告.
20. 张海磊*. X射线-光化学级联反应体系用于诱导水凝胶原位交联和降解. 中国化学会第35届学术年会，口头报告.
21. 张海磊*. X射线响应型水凝胶及其在生物医用材料领域的应用. 2026生物医药功能材料大会. 邀请报告.
22. Hailei Zhang. X-ray Induced Photochemistry cascade systems in polymer science enable diverse potential applications in the biomedical field. 8th International Symposium Frontiers in Polymer Science 2026, Oral report.
