马海云
一、个人简介
马海云, 河北保定人。浙江大学博士 (2005-2007)，美国密歇根大学(University of Michigan)博士后(2008-2011)。现为教授，博士研究生导师。迄今为止，在Advanced Functional Materials, Composites Part B:Engineering, Chemical Engineering Journal, Polymer Degradation and Stability等期刊发表SCI收录论文80余篇；先后主持完成国家自然科学基金面上项目、教育部博士点基金项目、教育部留学人员归国基金项目、河北省自然科学基金面上及青年基金项目等多项课题。主持省级一流本科课程、河北省精品在线开放课程《化学简史》、《无机及分析化学》；主编出版教材《化学简史》和《无机及分析化学》；主持完成两项河北省教学改革项目。
联系方式：E-mail: coffee1123@126.com；QQ：105098637
二、研究方向
1. 高分子材料的阻燃及高性能化：包括微纳米无机阻燃剂（纳米粘土、埃洛石纳米管、碳纳米材料、羟基锡酸盐等）的可控合成及其高分子复合材料的制备和构效关系研究；
2. 阻燃多功能气凝胶材料：基于超分子自组装的本质阻燃、隔热气凝胶材料；
3. 生物基气凝胶材料：生物质多糖、蛋白质、羟基磷灰石等为基体的气凝胶的设计及多功能研究；
4. 阻燃、火灾预警涂层材料：阻燃、基于热致变色、光致变色的火灾预警材料的开发和应用
三、主讲课程
1.《无机及分析化学》（河北省一流本科课程）
2.《化学简史》（河北省一流本科课程、河北省精品在线开放课程）
3.《General Chemistry》（双语课程）
4.《Inorganic chemistry》（外语授课，临床医学专业留学生班）
5.《魅力化学》
6.《化学与人类文明》（校级公选课）
7.《文献阅读与论文写作》（研究生课程）
三、代表性论文
2026年
1. Li Tingting, Zhang Haoxuan, Li Tianyu, Wang Liyong, Jia Guang, Xu Jianzhong, Ma Haiyun*. Reversible octahedral - tetrahedral coordination transformation in CoCl-based thermochromic films for early fire-warning and energy-efficient smart windows. Polymer Degradation and Stability, 2026, 248: 112066.
2. Tingting Li, Yufei Li, Haoxuan Zhang, Jianzhong Xu, Haiyun Ma*. Ginkgo-inspired polyvinyl alcohol/phosphomolybdic acid films: Mo6+/Mo5+ transition-driven multi-functionality for flame retardancy, fire warning and UV dosimetry. Chemical Engineering Journal, 546 (2026) 180058.
3. Chang Wang, Min Hu, Liyong Wang, Jianzhong Xu, Haiyun Ma*. Kapok fiber based holocellulose composite aerogels: Flame retardancy, anti-icing, self-deicing, thermal insulation and sound insulation. Polymer Degradation and Stability, 252 (2026) 112333.
4. Yajing Wang, Li Huo, Wenyan Zhao, Jianzhong Xu, Haiyun Ma. All-small-molecule self-assembled supramolecular aerogels with intrinsic flame retardancy and thermal insulation. Polymer Degradation and Stability, 250 (2026) 112177.
5. Yueqi Yang#, Wenyan Zhao#, Weihua Meng, Jianzhong Xu, Haiyun Ma*. College of Chemistry and Materials Science, Hebei University, Baoding, 071002, China b , Jianzhong XuFlame-retardant coating for flexible polyurethane foam with mechanical flexibility, self-healing capability, and rapid fire alarm response. Polymer Degradation and Stability, 253 (2026) 112416.
6. Saizheng Wang, Yueqi Yang, Lixia Zhang, Hongmei Liu, Haiyun Ma*. Supramolecular Phytic Acid/Melamine Self- Assembly Coatings for Flexible Polyurethane Foam With Superior Flame Retardancy and Fire- Warning. Journal of Applied Polymer Science, 2026; 143:e70395.
2025年
1. Zhang Hong, Ma Haiyun*, Gao Huiqi, Yang Le, Wang Chang, Jiao Yunhong, Xu Jianzhong*. Bird's nest inspired aerogels towards ultrahigh strength and robust flame retardancy at extreme environment, Composites Part B-Engineering 2025, 290: 111966.
2. Sun Sijia, Li Tingting, Yan Guoli, Jiao Yunhong, Xu Jianzhong, Ma Haiyun*. Reversible thermochromic aerogel coatings with superior flame retardancy and early fire warning. Chemical Engineering Journal. 2025, 518: 164618.
3. Wang Dan, Wang Chang, Li Tingting, Yan Guoli, Jiao Yunhong, Xu Jianzhong, Haiyun Ma*. APP-PER-MEL aerogel based on supramolecular assembly: New insight from conventional concept. Polymer Degradation and Stability. 2025, 234: 111197.
4. Wang Dan, Wang Yajing, Zhao Wenyan, Jiao Yunhong, Xu Jianzhong, Haiyun Ma*. Zn2+induced hierarchical all bio-based supramolecular folate/alginate dual network leading to ultra-light and fire-safety aerogels. Polymer Degradation and Stability. 2025, 241: 111606.
5. Wang Chang, Hu Min, Wu Yanji, Ma Haiyun*, Xu Jianzhong. Typha orientalis fibers based full biomass aerogel with robust flame retardancy and early fire warning. Polymer Degradation and Stability 2025, 242: 111637.
6. Huiqi Gao, Haiyun Ma*, Jinjin Cui, Xusheng Ge, Jiajun Tan, Jianzhong Xu*. Hierarchical hollow P-doped ZIF-8/MXene aerogel composites for phase change materials integrating shape stability, thermal energy storage, solar-thermal conversion and flame retardancy. Chemical Engineering Journal 2025, 526: 171306.
7. Wang Siqi, Yan Guoli, Zheng Yaduo, Jiao Yunhong, Xu Jianzhong, Ma Haiyun*. Full biomass-based polylactic acid (PLA) aerogel with robust flame retardancy and long-term early fire warning. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2025, 717: 136811.
8.Gao Huiqi, Ma Haiyun*, Cui Jinjin, Wang Chang, Zhang Hong, Jiao Yunhong, Xu Jianzhong*. Natural cellulose-based kapok fiber composite aerogel phase change materials with flame retardancy, fire warning, thermal energy storage and thermoelectric conversion. International Journal of Biological Macromolecules 2025, 319: 145740.
9. Yan Guoli Yan, Li Tingting, Wang Dan, Jiao Yunhong, Xu Jianzhong, Haiyun Ma*. Facile construction of a flexible metal-silk fibroin film with excellent flame retardancy for early fire warning. International Journal of Biological Macromolecules 2025, 307: 142364.
10. Gao Huiqi, Ma Haiyun*, Cui Jinjin, Tan Jiajun, Meng Weihua, Jiao Yunhong, Xu Jianzhong*. APP induced self-assembly of MXene aerogel composite phase change materials to integrate structural stability, flame retardancy, photo-thermal-electric conversion. Journal of Energy Storage 2025, 137: 118606.
2024年
1. Yang Le, Zhang Hong, Wang Chang, Pang Xiuyan, Jiao Yunhong, Xu Jianzhong, Ma Haiyun*, Novel Aerogels Based on Supramolecular G-Quadruplex Assembly with Intrinsic Flame Retardancy and Thermal Insulation. Journal of Colloid and Interface Science 2024, 672: 618-30.
2. Lou Yuanmeng, Ma Haiyun*, Jia Yuqiang, Sun Sijia, Wang Mei, Xu Jianzhong. One-pot synthesis of aluminum hypophosphite encapsulation in expanded halloysite lumen for reducing fire hazard and environmental pollution. Polymer Degradation and Stability. 2024;219:110599.
3. Wang Siqi, Yang Yueqi, Wang Chang, Jiao Yunhong, Wang Chunzheng, Ma Haiyun*. 'Dual cross-linked alginate/lignosulfonate-based aerogel with robust flame retardancy and antibacterial property', Cellulose, 2024, 31: 8787-8803.
4. Yang, Yueqi, Wang Saizheng, Wang Siqi, Wang Chang, Jiao Yunhong, Liu Hongmei, Ma Haiyun*. 'Biomimetic aerogel coatings for flexible polyurethane foams with superior flame retardancy, mechanical flexibility and antibacterial properties', Progress in Organic Coatings, 2024, 196: 108702.
2023年
1. Ma, Yiheng; Lou, Yuanmeng; Zhang, Hong; Yang, Le; Yang, Danqi; Xu, Jianzhong; Ma, Haiyun*, Construction of transition metal aromatic-sulfide polyphosphazene heterostructured nanowires for synergistic flame retardancy and smoke suppression. Chemical Engineering Journal 2023, 452, 139564.
2. Zhang, Hong; Ma, Haiyun*; Ma, Yiheng; Lou, Yuanmeng; Jiao, Yunhong; Xu, Jianzhong, Hierarchical boric acid/melamine aerogel based on reversible hydrogen bonds with robust fire resistance, thermal insulation and recycling properties. Composites Part B: Engineering 2023, 110507.
3. Lou, Yuanmeng; Su, Yanyue; Ma, Yiheng; Jiao, Yunhong; Xu, Jianzhong; Ma, Haiyun*, Flame retardancy and smoke suppression of multi-metal doped mesoporous bio-glass based hybrid microsphere on epoxy resin. Polymer Degradation and Stability 2023, 207, 110214.
4. Lou, Yuanmeng; Ma, Haiyun*; Su, Yanyue; Ma, Yiheng; Yang, Le; Zhang, Hong; Xu, Jianzhong, Cavity expansion and nanohybrid copper phytate@ halloysite coated with polyphosphazene for reducing smoke release and fire hazard of epoxy resin. Applied Clay Science 2023, 231, 106756.
5. Zhao Ang, Wei Chao, Xin Yue, Wang Xiaoli, Zhu Qingqing, Xie Jixing, Ma Haiyun, Xu Jianzhong, Wang Mei*. 'Pollution profiles, influencing factors, and source apportionment of target and suspect organophosphate esters in ambient air: A case study in a typical city of Northern China', Journal of Hazardous Materials, 2023, 444:130373.
2022年
1. Gao Quan, Zhao He, Zhou Xue-Ling, Liu Fu-Ya, Jiao Yun-Hong, Xie Ji-Xing, Qu Hong-Qiang, Xu Jian-Zhong, Ma Hai-Yun. 'Flame retardant, combustion and thermal degradation properties of polypropylene composites treated with the mixture of pentaerythritol, nickel hydroxystannate and expandable graphite', Polymer Degradation and Stability, 2022, 203: 110084.
2. Meng, Weihua, Yuying Song, Ke Zhai, Hang Di, Haiyun Ma, Xue Bi, Jianzhong Xu, and Lide Fang. 'Assembling MXene with bio-phytic acid: Improving the fire safety and comprehensive properties of epoxy resin', Polymer Testing, 2022, 110: 107564.
3. Rong, Xin, Xiaoxin Chen, Pan Li, Chenyang Zhao, Shan Peng, Haiyun Ma, and Hongqiang Qu. 'Mechanically durable anti-bacteria non-fluorinated superhydrophobic sponge for highly efficient and fast microplastic and oil removal', Chemosphere, 2022, 299:134493.
2021年
1. 董璐铭,苏衍跃,王春征,乔亚飞,陈雅君,马海云*. 微纳米钙钛矿型羟基锡酸钙的合成及对环氧树脂的阻燃性能[J]. 高等学校化学学报,2021(42)3:937-945
2. Dong, Luming; Su, Yanyue; Qiao, Yafei; Li, Ruotong; Xu, Jianzhong; Chen, Yajun; Ma, Haiyun*, Structure regulation of boron‐doped calcium hydroxystannate and its enhancement on flame retardancy and mechanical properties of PVC. Polym. Adv. Technol. 2021, 32 (4), 1831-1843.
2020年前
3. Danqi Yang, Luming Dong, Xudong Hou, Weikang Zheng, Jianzhong Xu, Haiyun Ma*. Synthesis of bio‐based poly (cyclotriphosphazene‐resveratrol) microspheres acting as both flame retardant and reinforcing agent to epoxy resin. Polymers for Advanced Technologies, 2020, 31(1), 135-145.
4. Danqi Yang, Chong Zhang, Luming Dong, Xudong Hou, Weikang Zheng, Jianzhong Xu, Haiyun Ma*. Synthesis and properties of SrSn (OH) 6 nanorods and their flame retardancy and smoke suppression effects on epoxy resin. Journal of Coatings Technology and Research, 2019, 16(6), 1715-1725.
5. Xiaodong Guo, Xiaowei Geng, Xiangdi Gao, Xin Zhang, Danqi Yang, Jianzhong Xu, Haiyun Ma*. Platinum Loaded Cyclomatrix Polyphosphazene Submicrospheres Improve Fire Retardancy of Epoxy with Very Low Addition. Composites Communications, 2019, 11:27-30.
10. Chong Zhang, Xiaodong Guo, Shuman Ma, Yanyang Zheng, Jianzhong Xu, Haiyun Ma*. Synthesis of a novel branched cyclophosphazene-PEPA flame retardant and its application on polypropylene. Journal of Thermal Analysis and Calorimetry, 2019, 137(1): 33-42.
11. Chong Zhang, Xiaodong Guo, Shuman Ma, Xiongrui Liu, Jianzhong Xu, Haiyun Ma*. Synthesis of an organic-inorganic hybrid strontium hydroxystannate nanorod and application as novel flame retardant. Materials Letters, 2018, 229: 297-300.
12. Xiaodong Guo, Xin Wang, Xiongrui Liu, Yanyang Zheng, Jianzhong Xu, Haiyun Ma*. Synthesis and application of a dual functional P/N/S‐containing microsphere with enhanced flame retardancy and mechanical strength on EP resin. Polymers for Advanced Technologies, 2018, 29(10): 2665-2673.
13. 赵师师, 贺梦, 刘雄瑞, 郭晓东, 张冲, 徐建中, 马海云*. 环交联聚磷腈微球的合成及阻燃聚碳酸酯的研究. 中国科学:化学, 2018, 48(3), 282-288.
14. Shishi Zhao, Meng He, Jianzhong Xu, Haiyun Ma*. Synthesis of a functionalised phosphazene-containing nanotube/epoxy nanocomposite with enhanced flame retardancy. Micro & Nano Letters, 2017, 12(6), 401-403.
15. Taotao Nie, Meng He, Min Ge, Jianzhong Xu, Haiyun Ma*. Fabrication and structural regulation of PLLA porous microspheres via phase inversion emulsion and thermally induced phase separation techniques. Journal of Applied Polymer Science, 2017, 134(22): 44885.
16. Taotao Nie, Li Xue, Min Ge, Haiyun Ma*, Jinchao Zhang. Fabrication of poly (L-lactic acid) tissue engineering scaffolds with precisely controlled gradient structure. Materials Letters, 2016, 176, 25-28.
17. Ma Haiyun, Song Pingan, Fang Zhengping. Flame retarded polymer nanocomposites: development, trend and future perspective[J]. Science China Chemistry, 2011, 54: 302-313.
18. Ma, Haiyun; Hu, Jiang; Ma, P. X., Polymer Scaffolds for Small-Diameter Vascular Tissue Engineering. Advanced Functional Materials 2010, 20 (17), 2833-2841.
19. Ma, Haiyun; Tong, Lifang.; Xu, Zhongbin; Fang, Zhengping, Functionalizing Carbon Nanotubes by Grafting on Intumescent Flame Retardant: Nanocomposite Synthesis, Morphology, Rheology, and Flammability. Advanced Functional Materials 2008, 18 (3), 414-421.
20. Ma, Haiyun; Tong, Lifang; Xu, Zhongbin; Fang, Zhengping, Synergistic effect of carbon nanotube and clay for improving the flame retardancy of ABS resin. Nanotechnology 2007, 18 (375602), 14026-14029.
21. Ma, Haiyun; Tong, Lifang; Xu, Zhongbin; Fang, Zhengping, Clay network in ABS-graft-MAH nanocomposites: Rheology and flammability. Polymer Degradation and Stability 2007, 92 (8), 1439-1445.
四、科研项目
1.钙钛矿型锡酸盐微纳米结构调控及其复合材料的阻燃机理及构效关系研究（项目批准号：52173073），国家自然科学基金面上项目（2022-2025，主持人）
2.金属复盐与环交联聚磷腈杂化微纳米阻燃体系的构建及阻燃机理研究（项目批准号：E2019201181），河北省自然科学基金项目（2019-2021，主持人）
3.聚乳酸纳米复合材料组织工程支架及生物纳米效应（项目批准号：20131301120006）；教育部博士点基金项目(2013-2015，支持人)
4.具有功能梯度结构的组织工程支架的制备及纳米生物效应的研究，教育部留学回国人员科研启动基金（2013-2015，主持人）
5.具有多级功能梯度结构的纳米复合纤维组织工程支架及其生物纳米效应研究（项目批准号：E201201230），河北省自然科学基金（2013-2015，主持人）
五、获奖
1. 第六届河北大学最受学生喜爱教师称号（2026年）
2. 第三届河北大学最受学生喜爱教师称号（2023年）
3. 第八届河北大学教学成果二等奖（排名第一，2019年）
4. 第六（2015年）、七（2017年）、八（2019年）届河北大学青年教师教学大赛三等奖
